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Solving geological and historical puzzles with advanced gemologic techniques: The Franco Dávila (1772) precious opal case

机译:用高级宝石学技术解决地质和历史难题:佛朗哥·达维拉(1772)珍贵的蛋白石盒

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[EN] The large precious opal weighting 33 grams fitted in a silver jewel and exposed to visitors at the Museo Nacional de Ciencias Naturales (MNCN) is well documented in: (i) its own mounting (1772), (ii) at the 775 document of the Archive of the MNCN and (iii) the 395 specimen described in the of Pedro Franco Dávila catalogue. The X-ray diffractogram (XRD) performed onto the opal block is very similar to other opals of volcanic origin containing varied amounts of cristobalite, tridymite and amorphous silica. The Raman spectrum shows a band peaked at 242, 343 and 416 cm-1 associated with O-Si-O stretching groups; other spectral band peaked at 780 and 819 cm-1 corresponding to vibration of symmetrical O-Si-O rings of 3 and 4 link members, plus other minor bands. The Raman spectrum is also very similar to those observed in Mexican opals of volcanic origin containing an spectral band of stretching nodes ¿1 (OH) at 3233, 3393, 3511, 3628 cm-1 related to OH groups with hydrogen bonds of isolated silanol groups. The interferometric confocal dual microscope 3D (MCI3D), which is a nondestructive facility of high resolution and LED technology reveals the geometry of graver tools on the silver jewel and the computed tomography X-ray highlights the opal cutting as a squared princess type and silver chloride infillings of a crack probably caused by a shock on a corner. Under the scanning electron microscope we observed barite, sealed veins of silica rich in Mn and opal with high contents of Al and K which, along with the historical data, the piece can be attributed to the historical site of opals hosted in Slovakia andesite rocks, this data explains the optical light behavior in the cabochon. The silver jewel has large amounts of Hg and AgCl indicating amalgam method. In addition the natural AgS2 phases probably come from Nueva España (year 1772) in full production of silver in such time. The association of new analytical non-destructive techniques combines the preservation of samples together with significant analytical data allowing us to deduce genetic mineral processes, provenances and manufacturing techniques of materials. These facilities allow the characterization, interpretation, conservation and enhancement of cultural and archaeological heritage.
机译:[EN]珍贵的蛋白石重33克,装在银色珠宝中,在国家自然博物馆(MNCN)上对游客暴露,其记录如下:(i)它自己的底座(1772),(ii)775 MNCN档案的文件,以及(iii)Pedro FrancoDávila目录中描述的395个样本。在蛋白石块上进行的X射线衍射图(XRD)与火山成因的其他蛋白石非常相似,其中包含各种量的方石英,鳞石英和无定形二氧化硅。拉曼光谱显示出与O-Si-O拉伸基团相关的在242、343和416 cm-1处的峰带。其他光谱带在780和819 cm-1处达到峰值,这对应于3个和4个连接成员的对称O-Si-O环的振动,以及其他次要带。拉曼光谱也与在墨西哥火山岩蛋白石中观察到的光谱非常相似,该墨西哥蛋白石在3233、3393、3511、3628 cm-1处具有与带有分离的硅烷醇基团氢键的OH基有关的拉伸节点Â1(OH)的光谱带。干涉共聚焦双显微镜3D(MCI3D)是一种无损的高分辨率和LED技术,揭示了银珠宝上的雕刻工具的几何形状,计算机断层摄影X射线突出了蛋白石切割成方形的公主型和氯化银裂纹的填充物可能是由于拐角处的冲击而引起的。在扫描电子显微镜下,我们观察到重晶石,富含Mn和蛋白石的硅石密封脉脉,其中Al和K的含量很高,再加上历史数据,这可归因于斯洛伐克安山岩中的蛋白石历史遗迹,此数据解释了凸圆面中的光学行为。该银珠宝中含有大量的Hg和AgCl,表明存在汞齐法。此外,自然的AgS2相可能来自NuevaEspaña(1772年),并且在此期间已大量生产白银。新的非破坏性分析技术的结合将样品的保存与重要的分析数据结合在一起,使我们能够推断出遗传矿物的过程,来源和材料的制造技术。这些设施可以对文化和考古遗产进行表征,解释,保护和增强。

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